Justin R. Walensky

Justin R. Walensky
Associate Professor and Associate Chair for Undergraduate Studies
Phone: 
573-882-0608
Office: 
203 Chemistry
Research Emphasis: 

Synthesis; Actinide chemistry; Chalcogen and pnictogen chemistry; Density Functional Theory; Group 11 chemistry

Education: 

B.A. Chemistry, New College of Florida, 2005
Ph.D. Chemistry, University of California, Irvine, 2009

Professional Experience: 

Associate Professor, Missouri, 2016-
Associate Chair for Undergraduate Studies, 2015-
Assistant Professor, Missouri, 2011-2016
Postdoctoral Research Associate, Texas A&M University, 2010

Honors and Awards:
2018, Fuldner Faculty Fellow, MU Department of Chemistry
2017, MU President's Award for Early Career Excellence
2017, Faculty Fellowship Summer Institute in Israel
2015-2020, Department of Energy Early Career award
2013, Southeastern Conference (SEC) travel grant award
2011-2016, Nuclear Forensics Junior Faculty Award, Department of Homeland Security, Domestic Nuclear Detection Office
2011, CIBA Young Scientist Travel Award, American Chemical Society
2010, Robert A. Welsh Foundation Postdoctoral Fellowship
2009, Glenn T. Seaborg Institute Fellowship, Los Alamos National Laboratory
2006, Chemistry Graduate Student Teaching Award: Contributions to the Chemistry Department Teaching Program by a First Year Teaching Assistant

Research: 

Our research is divided into three areas: 1) Structure, bonding, spectroscopy, and reactivity of actinide complexes, 2) Group 11 reactivity, and 3) Computational chemistry

1) Actinide Chemistry
We are interested in exploring the fundamental nature of actinide-ligand bonding with soft donor ligands such as the heavier chalcogens and pnictogens. Soft donor ligands are relevant to separation methods as sulfur-based ligands have been shown to have more selectivity towards actinides over lanthanides. In our overall goal to provide insight into actinide-ligand bonding we have two objectives: 1) To investigate the molecular and electronic structure of organometallic complexes of thorium, uranium, and neptunium with soft donor ligands such as S, Se, Te, P, and As having sigma (single) bonds as well as sigma and pi (double) bonds. Reactivity patterns are established and compared to their first row counterparts (O and N). 2) The fundamental coordination chemistry and properties of neptunium, especially Np(III) and Np(IV) complexes.

Publications in this area:
Inorg. Chem. 2013, 52, 10623
Eur. J. Inorg. Chem. 2013, 4050 (special issue on small molecule activation)
Radiochim. Acta 2013, 101, 631
Dalton Trans. 2015, 44, 2693 (special issue on f-element chemistry)
Radiochim. Acta 2015, 102, 49
Anal. Chem. 2015, 87, 4210
Eur. J. Inorg. Chem. 2015, 2996
J. Coord. Chem. 2015, 68, 3718
J. Am. Chem. Soc. 2015, 137, 14846
Inorg. Chem. 2015, 54, 11625
J. Coord. Chem. 2016, 69, 1904 (special issue on Emerging Leaders in Coordination Chemistry)
Dalton Trans. 2016, 45, 10042 (special issue on New Talent: Americas)
Inorg. Chem. 2016, 55, 12675
Chem. Commun. 2016, 52, 14373
J. Radioanal. Nucl. Chem. 2017, 311, 35
Angew. Chem. Int. Ed. 2017, 56, 12925
Chem. Eur. J. 2017, 23, 16748
J. Organomet. Chem. 2018, 857, 159 (special issue for Bill Evans)
Inorg. Chem. 2018, 57, 7270
Organometallics 2018, 37, 1884
Dalton Trans. 2018, 47, 8189
Inorg. Chem. 2018, 57, 10518
Chem. Commun. 2018, 54, 10435
Angew. Chem. Int. Ed. 2018, 57, in press
 

 

2) Transition Metal and Main Group Chemistry
Group 11 elements have importance as fluorescent probes, sensors, and biological systems. The reactivity of dinuclear group 11 complexes, especially with amidinate ligands, is being investigated to examine their luminescence, metallophilic interactions, and redox chemistry.

The chemistry of chalcogen and pnictogen elements is also of interest, especially the design of new ligands to support our actinide chemistry or the synthesis of fluorescent compounds in collaboration with Gary Baker's group.

Publications in this area:
Polyhedron 2013, 54, 300
Inorganics 2014, 2, 540 (special issue on Frontier in Gold Chemistry)
Inorg. Chem. 2014, 53, 11357
Organometallics 2015, 34, 3 (selected as issue cover)
Polyhedron 2015, 100, 333
Inorg. Chem. 2015, 54, 8509
Dalton Trans. 2016, 45, 14265
Dalton Trans. 2017, 46, 10867

 

3) Computational Chemistry
We collaborate with way more talented synthetic chemists (mostly Suzanne Bart) to help with electronic structure calculations.

Publications in this area: 
J. Am. Chem. Soc. 2011, 133, 6894
J. Am. Chem. Soc. 2011, 133, 11732
Inorg. Chem. 2013, 52, 3556 (Forum Article)
Chem. Eur. J. 2013, 19, 10162
Nature Chem. 2014, 6, 919
Inorg. Chem. 2014, 53, 12977
Organometallics 2015, 34, 3930

 

Select Publications: 

See the group website for a list of publications.

Research Division: